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IEC 62321-11 Ed. 1.0 b:2023
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  • IEC 62321-11 Ed. 1.0 b:2023

IEC 62321-11 Ed. 1.0 b:2023

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Determination of certain substances in electrotechnical products – Part 11: Tris(2-chloroethyl) phosphate (TCEP) in plastics by gas chromatography-mass spectrometry (GC-MS) and liquid chromatography-mass spectrometry (LC-MS)

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Full Description

This part of IEC 62321 specifies two different techniques for the determination of tris(2-chloroethyl) phosphate (TCEP) in plastics, the GC-MS or LC-MS method, both of which are applicable to quantitative analysis.

These two techniques are applicable to use with polyurethane, polyvinylchloride, and polyethylene materials containing TCEP between 200 mg/kg to 2 000 mg/kg.

These test methods do not apply to plastic materials having a processing temperature higher than 230 °C.

GC-MS using a pyrolyser/thermal desorption accessory (Py/TD-GC-MS) technique is described in Annex A and can be used for the screening of TCEP in plastics.

NOTE TCEP starts thermal decomposition at approximately 230 °C. Polymer types that have a processing temperature into shapes of plastics (e.g. pellets, moulded parts or sheets) not exceeding the decomposition temperature can contain TCEP.

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